Synthesis of Novel Bis- and Tris(tetrathiafulvalene) Amphiphiles for Use in Langmuir-Blodgett Film Deposition

Roland P. Parg; Jeremy D. Kilburn; Michael C. Petty; Christopher Pearson; Timothy G. Ryan

doi:10.1055/s-1994-25534

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Synthesis 1994; 1994(6): 613-618
DOI: 10.1055/s-1994-25534

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Synthesis of Novel Bis- and Tris(tetrathiafulvalene) Amphiphiles for Use in Langmuir-Blodgett Film Deposition

Roland P. Parg^* , Jeremy D. Kilburn, Michael C. Petty, Christopher Pearson, Timothy G. Ryan

^*Department of Chemistry, University of Southampton, Highfield, Southampton SO9 5NH, England

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Publication Date:
17 September 2002 (online)

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Bis- and tris(tetrathiafulvalene) (TTF) amphiphiles 17-20 have been prepared by coupling together the mono-TTF derivatives 7, 9, 14 and 16. These novel bis- and tris-TTF amphiphiles showed improved stability in monolayer formation on a water surface, as compared to the mono-TTF-derivatives, and were deposited to give Langmuir-Blodgett (LB) films.